N-acylation: an effective method for reducing the LUMO energy levels of conjugated polymers containing five-membered lactam units.
نویسندگان
چکیده
N-acylation was studied as a method for reducing the LUMO energy levels of benzodipyrrolidone-based polymers. The N-acylated polymers showed reduced LUMO levels and improved reversibility of reductive doping compared with N-alkylated polymers. This method may also apply in other conjugated polymers with lactam repeating units.
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ورودعنوان ژورنال:
- Chemical communications
دوره 48 55 شماره
صفحات -
تاریخ انتشار 2012